Development of ozone reactivity scales for volatile organic compounds

project summary

Publisher: U. S. Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory in Research Triangle Park, NC

Written in English
Published: Downloads: 137
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Subjects:

  • Ozone.,
  • Volatile organic compounds.

Edition Notes

StatementWilliam P.L. Carter.
ContributionsAtmospheric Research and Exposure Assessment Laboratory (U.S.)
The Physical Object
FormatMicroform
Pagination1 v.
ID Numbers
Open LibraryOL15369697M

  Development of a Direct Reactivity Measurement Method for Volatile Organic Compounds Wiliam P.L. Carter, Ph.D., Air Pollution Research Center, College of Engineering Center for Environmental Research and Technology, University of California, Riverside. This paper addresses the impact of California phase 2 reformulated gasoline (RFG) on the composition and reactivity of motor vehicle exhaust and evaporative emissions. Significant changes to gasoline properties that occurred in the first half of included an increase in oxygen content; decreases in alkene, aromatic, benzene, and sulfur contents; and modified distillation properties. Emissions Modeling of Specific Highly Reactive Volatile Organic Compounds (HRVOC) in the Houston-Galveston-Brazoria Ozone Nonattainment Area. The development of a strategy for reducing ozone in HGB is complicated by the many factors There are several reactivity scales in use today. The two most popular are the OH and the MIR. The secondary pollutants formation in the atmosphere, such as ozone (O 3), comes from the reactions between volatile organic compounds (VOCs) and the photochemical oxidants in the presence of oxygen and nitrogen oxides (NO x).The understanding of VOCs reactivity emitted by light duty vehicles is very important to construct reactivity scales regarding ozone formation.

As noted in Chapter 1, ozone is formed by chemical reactions involving volatile organic compounds (VOCs) and carbon monoxide (CO) in the presence of nitrogen oxides (NO x) and might expect, therefore, that the severity of ozone pollution in a given region can be reduced by lowering the emissions of VOCs, CO, NO x, or any combination thereof. age to lung tissue and plants. This “bad” ozone forms when sunlight initiates chemical reactions in the air involving pollutants, particularly a family of gases called nitrogen oxides (released from vehicles and industry during the combustion process) and with volatile organic compounds (carbon-containing. From Carter's article on “Development of Ozone Reactivity Scales for Volatile Organic Compounds,” the term “base ROG mixture” means the mixture of Reactive Organic Gases (ROGs) initially present or emitted in the Empirical Kinetic Modeling Approach (EKMA) scenarios except for biogenic VOCs, VOCs present aloft, or VOCs added for the. We report on the development of a modelling consortium for chemistry in indoor environments that connects models over a range of spatial and temporal scales, from molecular to room scales and from sub-nanosecond to days, respectively. Our modeling approaches include molecular dynamics (MD) simulations, kinet Environmental Science: Processes & Impacts: Recent Review Articles Best .

Ozone Reaction with Various Compounds. Many organic and inorganic compounds react with ozone. These reactions can vary greatly depending upon the state of ozone (gaseous or aqueous), and the other chemicals involved in the reaction. Below is an outline of basic chemical reactions between ozone and certain compounds.   The remaining 10 percent of atmospheric ozone is located in the troposphere, which extends from the surface of the Earth to the stratosphere. Ozone in the troposphere is not emitted directly into the air as a gas, but is formed through the photochemical reaction of nitrogen oxides (NOx) and volatile organic compounds (VOCs).

Development of ozone reactivity scales for volatile organic compounds Download PDF EPUB FB2

DEVELOPMENT OF OZONE REACTIVITY SCALES FOR VOLATILE ORGANIC COMPOUNDS by William P. Carter Published in the Journal of the Air and Waste Management Association pages Janu Statewide Air Pollution Research Center, and College of Engineering Center for Environmental Research and Technology University of California.

Abstract. This paper discusses methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs). Photochemical mechanisms for the atmospheric reactions of VOCs were used to calculate their effects on ozone formation under various NO x conditions in model scenarios representing 39 different urban areas.

Their effects on ozone were Cited by: Methods for developing a numerical scale ranking reactivities of volatile organic compounds (VOCs) towards ozone formation were investigated. Effects of small VOC additions on ozone formation (incremental reactivities) were calculated for types of VOCs in model scenarios representing a variety of single-day pollution episodes.

Abstract This paper discusses methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs). Photochemical mechanisms for the atmospheric reactions of VOCs were used to calculate their effects on ozone formation under various NOx conditions in model scenarios representing 39 different urban areas.

PB EPA/// September DEVELOPMENT OF OZONE REACTIVITY SCALES FOR VOLATILE ORGANIC COMPOUNDS William P. Carter Statewide Air Pollution Research Center University of California Riverside, CA Cooperative Agreement No. CR August Project Officer Joseph J.

Bufalini Chemical Processes and Characterization Division Atmospheric. The complete report, entitled "Development of Ozone Reactivity Scales for Volatile Organic Compounds" (Order No. PB /AS; Cost: $, subjectto change) will be available only from: National Technical Information Service Port Royal Road Springfield, VA Telephone: The EPA Project Officer can be contacted at.

Abstract. Methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs) are discussed. Photochemical mechanisms for the atmospheric reactions of VOCs were used to calculate their effects on ozone formation under various NO x conditions in model scenarios representing 39 different urban areas.

Carter 10/17/ VOC Reactivity Scales 1 Development of Reactivity Scales for Volatile Organic Compounds Topics • VOCs and air quality • Factors affecting ozone reactivity and ozone reactivity scales • Use of VOC reactivity in ozone control strategies • Quantifying other VOC impacts: fine particle pollution; global.

Carter, “Development of Ozone Reactivity Scales for Volatile Organic Compounds,” Journal of the Air and Waste Management Association, Vol. 44,pp. has been cited by the following article: TITLE: Biogenic Isoprene and Its Impact on Human Health in Dependence on Meteorological Conditions.

W.P.L. CarterDevelopment of ozone reactivity scales for volatile organic-compounds Journal of Air and Waste Management Association, 44 (7) (), pp. Google Scholar. Development of ozone reactivity scales for volatile organic compounds.

Air Waste Management Association, 44, has been cited by the following article: Article. Municipal Solid Waste in Delhi: Ambient VOCs, Health Risks, GIS Modeling, Management, Policy Intervention, Climate Change and a Manmade Disaster in Waiting.

W.P.L. Carter, "Development of Ozone Reactivity Scales for Volatile Organic Compounds," Journal of the Air and Waste Management Association, 44,() W.P.L. Carter and F.W. Lurmann, "Evaluation of a Detailed Gas Phase Atmospheric Reaction Mechanism Using Environmental Chamber Data," Atmos.

Environ., 25A, (). The SAPRC mechanisms have the ability to optionally include separate representations of the reactions of hundreds of different types of VOCs. Generally these are not all included in the airshed model at the same time, but selected compounds can be represented separately for the purpose of calculating reactivity scales or for toxics modeling, or mechanisms for groups of compounds can be.

5 hours ago  Carter, W.P.L. Development of ozone reactivity scales for volatile organic compounds. Air Waste44, – [Google Scholar] Carter, W.P.L. Updated maximum incremental reactivity scale and hydrocarbon bin reactivities for regulatory applications. Calif. Air Resour.

Board Contract, [Google Scholar]. [1] A source‐oriented SAPRC‐99 gas phase photochemical mechanism was incorporated into the Community Multiscale Air Quality (CMAQ) model to determine the contributions of volatile organic compounds (VOCs) to predicted net ozone (O 3) formation rates during the Texas Air Quality Study (TexAQS) from 16 August to 7 September Contributions from biogenic sources, diesel.

Ozone in photochemical smog is formed from the gas-phase reactions of oxides of nitrogen (NOx) and volatile organic compounds (VOCs). VOCs differ in their effects on ozone formation, and methods for quantifying these differences would aid in the development of cost-effective ozone control strategies.

Development of Methods to Compare VOC Reactivities To use the concept of reactivity a method is needed to quantify the impact of each VOC on ozone formation. One tool that allows for ozone measurement is a reactivity scale. Many scales have been proposed to quantify the ozone formation potential of VOCs.

ABSTRACT A detailed atmospheric photochemical mechanism which had been previously used in model calculations for developing ozone reactivity scales for volatile organic compounds (VOCs) was evaluated by comparing its predictions with measurements of incremental reactivities in an environmental chamber system.

Carter, W. and I. Malkina; Development and application of improved methods for measurement of ozone formation potentials of volatile organic compounds, Final report to California Air Resources Board Contract 97–, May 22 (). Volatile Organic Compounds (VOC's) react with nitrogen oxides on hot summer days to form ozone (smog).

Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals. DEVELOPMENT OF OZONE REACTIVITY SCALES FOR VOLATILE ORGANIC COMPOUNDS Manuscript date: Janu Published in the Journal of the Air and Waste Management Association, pagesView Abstract Download Document; William P.

Carter, John A. Pierce, Dongmin Luo, and Irina L. Malkina. 5 hours ago  Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest. Atmos. Chem. Phys.18, – [CrossRef] Carter, W.P.L. Development of ozone reactivity scales for volatile organic compounds.

Air Waste44, – [CrossRef] Ozone, NO x and VOC [Return to Table of Contents] Ozone formation Factors affecting O 3-NO x-VOC sensitivity Uncertainty in O 3-NO x-VOC sensitivity predictions. Ozone formation is driven by two major classes of directly emitted precursors: nitrogen oxides (NO x) and volatile organic compounds (VOC).The relation between O 3, NO x and VOC is driven by complex.

Ozone formation is non-linear process and is produced from the photochemical interactions of volatile organic compounds (VOCs) and oxides of nitrogen (NOx) in the troposphere.

Generally, MIR (Maximum Incremental Reactivity) scale is one of the popular ones in the assessment of ozone formation potential of various VOC compounds.

Volatile organic compounds (VOCs) are major precursors for ozone and secondary organic aerosol (SOA), both of which greatly harm human health and significantly affect the Earth's climate. Environmental context Megacities are huge hotspots of pollutants that have an impact on atmospheric composition on local to larger scales.

This study presents for the first time detailed results of measurements of volatile organic compounds in Paris and shows that, whereas non-methane hydrocarbons are mainly of local and regional origin associated with traffic emissions, a significant.

The incremental reactivity (IR) and relative incremental reactivity (RIR) of carbon monoxide and 30 individual volatile organic compounds (VOC) were estimated for the South Coast Air Basin using two photochemical air quality models: a 3-D, grid-based model and a vertically resolved trajectory model.

Both models include an extended version of the SAPRC99 chemical mechanism. William P. Carter, Development of Ozone Reactivity Scales for Volatile Organic Compounds, Journal of the Air and Waste Management Association,July I want to hear from you.

Tell me how we can improve. The Environmental Protection Agency (EPA) encourages States to consider recent scientific information on the photochemical reactivity of volatile organic compounds (VOC) in the development of State implementation plans (SIPs) designed to meet the national ambient air quality standard (NAAQS) for ozone.

The Science of Volatile Organic Compound Photochemical Reactivity. The photochemical reactivity of a VOC is a measure of its potential to impact ozone levels.

Individual VOCs vary in the amount of ozone potentially formed once they are emitted in the air; this is called “reactivity.”Distinguishing between more reactive and less reactive VOCs will further or more.

Page 6 VOCs and No x: Relationship to Ozone and Associated Pollutants Introduction. Ozone (O 3) is produced in the troposphere as a result of a complex set of reactions that involve volatile organic compounds (VOCs) and oxides of nitrogen (NO x).These reactions are discussed in detail in Chapter 5.

Because the initial atmospheric concentrations (and corresponding emissions) of VOCs and NO.Methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs) are discussed. Photochemical mechanisms for the atmospheric reactions of VOCs were used to calculate their effects on ozone formation under various NO x conditions in model scenarios representing 39 different urban areas.Ozone is a secondary pollutant formed by complex chemical reactions between nitrogen oxides and volatile organic compounds in the presence of sunlight.

These precursors to ozone are each produced primarily by a variety of human activities, including burning of fossil fuels and various industrial processes.